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Bulletin of the Faculty of Education, Wakayama University. Natural science 53
2003-02-27 発行
Oxidation of Benzyl Alcohols with Tetraalkylammonium Dichlorobromate(1-)
テトラアルキルアンモニウムジクロロブロメート(1-)によるベンジルアルコール類の酸化反応
Negoro, Takeshi
Tanaka, Takanori
Taketomo, Hisae
Fujita, Yuki
Yano, Kozue
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eng
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7
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18
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The reaction of various substituted benzyl alcohols with an equimolar amount of tetraalkylammonium dichlorobromate(1-) (1) in water-hexane in the presence of sodium hydroxide gave the corresponding benzaldehydes and with 2 equiv. of 1 in water in the presence of sodium hydroxide (subsequent acid hydrolysis) gave the corresponding benzoic acids, respectively, in good yields. Meanwhile, the reaction of methoxy-substituted benzyl alcohols in the presence of disodium phosphate gave nuclear bromo-substituted benzyl alcohols.
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