ID 1443
FullText File
Title Alternative
Phase Transition and Thermochromism in Bromo-Bridged 1-D Pt Complex Studied by DSC, X-ray and UV-Vis Spectrum Measurements
Authors
Nakamura, Akane
DOI
Journal Title
Bulletin of the Faculty of Education, Wakayama University. Natural science
ISSN
13424645
NCID
AN00257977
Volume
56
Start Page
31
End Page
33
Published Date
2006-02-28
Language
jpn
Abstract Alternative
We performed the DSC, X-ray and UV-Vis spectrum measurements on [Pt (en)_2] [PtBr_2 (en)_2] (ClO_4)_4 in which a modification was reported by crystallizing from aqueous solution below room temperature. A metastable phase crystallizing below room temperature showed a different phase transition with thermochromism at ca. 380K to the stable form. The obtained X-ray powder patterns confirmed that the phase transition at 380K was transformation into the stable form.
Content Type
Departmental Bulletin Paper
Text Version
publisher
Accession No.
KJ00004438614