ID 1427
フルテキストファイル
その他のタイトル(欧)
Valence Structures and Spin Dynamics in One-Dimensional Mixed-Metal Complexes, [Cu (chxn)_2] [PtX_2 (chxn)_2]X_4 (X:CI, Br)
作成者
青木 裕史
DOI[info:doi/]
掲載誌名
和歌山大学教育学部紀要. 自然科学
ISSN
13424645
NCID
AN00257977
55
開始ページ
1
終了ページ
3
発行日
2005-02-28
本文言語
日本語
抄録(欧)
We measured the Raman, UV-visible and ^<13>C CP-MAS NMR spectra of halogen-bridged 1-D Cu-Pt mixed-metal complexes, [Cu (chxn)_2] [PtX_2 (chxn) 2]X_4 (X : Cl and Br), consisting of -X-Cu-X-Pt-X-chain. The Raman spectra showed an overtone progression of symmetric stretching mode of Pt (IV) -Cl atoms and the fine structures with halogen isotopic splitting in Pt-Cl band below ca. 50 K. The broad carbon signals of the ^<13>C NMR spectra observed at room temperature are attributable to strong paramagnetic effect from Cu (II) sites. This result is supported by the weak antiferromagnetic interactions between Cu (II) sites in the chain.
資料タイプ
紀要論文
著者版フラグ
出版者版
アクセション番号
KJ00004292656