テトラアルキルアンモニウムジクロロブロメート(1-)によるベンジルアルコール類の酸化反応

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ID 1404
FullText File
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Title Alternative
Oxidation of Benzyl Alcohols with Tetraalkylammonium Dichlorobromate(1-)
Authors
Negoro, Takeshi
Tanaka, Takanori
Taketomo, Hisae
Fujita, Yuki
Yano, Kozue
DOI
10.19002/AN00257977.53.7
Journal Title
Bulletin of the Faculty of Education, Wakayama University. Natural science
ISSN
13424645
NCID
AN00257977
Volume
53
Start Page
7
End Page
18
Order
04
Published Date
2003-02-27
Language
eng
Abstract Alternative
The reaction of various substituted benzyl alcohols with an equimolar amount of tetraalkylammonium dichlorobromate(1-) (1) in water-hexane in the presence of sodium hydroxide gave the corresponding benzaldehydes and with 2 equiv. of 1 in water in the presence of sodium hydroxide (subsequent acid hydrolysis) gave the corresponding benzoic acids, respectively, in good yields. Meanwhile, the reaction of methoxy-substituted benzyl alcohols in the presence of disodium phosphate gave nuclear bromo-substituted benzyl alcohols.
Content Type
Departmental Bulletin Paper
Text Version
publisher
Accession No.
KJ00000162679