-M(II)-X-Pt(IV)-X-型錯体[M(en)_2][PtX_2(en)_2](NO_3)_4(M: Pd, Pt; X: Cl, Br)における^<13>C固体NMR、ESR、IRの研究

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Title Alternative
^<13>C Solid NMR, ESR and IR Studies on -M(II)-X-Pt(IV)-X- Type Complexes, [M(en)_2] [PtX_2(en)_2] (NO_3)_4 (M: Pd, Pt; X: Cl, Br)
Authors
KIMURA, Noriyoshi Faculty of Education 和歌山大学研究者総覧 researchmap
Hasegawa, Junko
KISODA, Kenji Faculty of Education 和歌山大学研究者総覧 researchmap
Ikeda, Ryuichi
Self DOI
10.19002/AN00257977.54.29
Journal Title
Bulletin of the Faculty of Education, Wakayama University. Natural science
ISSN
13424645
NCID
AN00257977
Volume
54
Start Page
29
End Page
32
Order
06
Published Date
2004-02-27
Language
eng
Abstract Alternative
IR and ^<13>C NMR measurements in hetero-metal complexes, [Pd(en)_2] [PtX_2(en)_2] (NO_3)_4 (X: Cl, Br) afforded two kinds of signals assignable to Pd and Pt moieties, indicating the formation of the Pd(II)-X-Pt(IV)-X-type chain structure. Weak ESR signal observed in [Pt(en)_2] [PtCl_2(en)_2] (NO_3)_4 suggested the formation of only small amounts of spinsoliton.
Content Type
Departmental Bulletin Paper
Text Version
publisher
Accession No.
KJ00004258256