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Bulletin of the Faculty of Education, Wakayama University. Natural science 54

2004-02-27 発行

^<13>C Solid NMR, ESR and IR Studies on -M(II)-X-Pt(IV)-X- Type Complexes, [M(en)_2] [PtX_2(en)_2] (NO_3)_4 (M: Pd, Pt; X: Cl, Br)

-M(II)-X-Pt(IV)-X-型錯体[M(en)_2][PtX_2(en)_2](NO_3)_4(M: Pd, Pt; X: Cl, Br)における^<13>C固体NMR、ESR、IRの研究

KIMURA, Noriyoshi Faculty of Education 和歌山大学研究者総覧 researchmap

Hasegawa, Junko

KISODA, Kenji Faculty of Education 和歌山大学研究者総覧 researchmap

Ikeda, Ryuichi

FullText File

KJ00004258256.pdf 186 KB

Self DOI

10.19002/AN00257977.54.29

About This Article

Language

eng

Start Page

29

End Page

32

Abstract Alternative

IR and ^<13>C NMR measurements in hetero-metal complexes, [Pd(en)_2] [PtX_2(en)_2] (NO_3)_4 (X: Cl, Br) afforded two kinds of signals assignable to Pd and Pt moieties, indicating the formation of the Pd(II)-X-Pt(IV)-X-type chain structure. Weak ESR signal observed in [Pt(en)_2] [PtCl_2(en)_2] (NO_3)_4 suggested the formation of only small amounts of spinsoliton.

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KJ00004258256.pdf 186 KB

Total Contents

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