ID | 1465 |
FullText File | |
Title Alternative | Oxidation of Sulfides with Tetraalkylammonium Dichlorobromate(1-)
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Authors |
NEGORO, Takeshi
ZINZAI, Ken
NEGORO, Shiho
MAEDA, Michiyo
IIBOSHI, Emika
TSUJIMOTO, Chie
AYABE, Miki
MATSUMOTO, Atsusi
MATSUOKA, Hiroko
NAKAMURA, Fumiko
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Self DOI | |
Journal Title |
Bulletin of the Faculty of Education, Wakayama University. Natural science
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ISSN | 13424645
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NCID | AN00257977
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Volume | 58
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Start Page | 19
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End Page | 29
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Order | 05
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Published Date | 2008-02-29
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Language |
jpn
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Abstract Alternative | The oxidation of aliphatic sulfides with a nearly equimolar amount of tetrabutylammonium (or benzyltrimethylammonium) dichlorobromate(1-) in aqueous sodium hydroxide and dichloromethane, in aqueous acetic acid, or in aqueous pyridine gave the corresponding sulfoxides in good yields. Meanwhile, the reaction of aromatic sulfides such as diphenyl sulfide and thianthren depends on the oxidation methods and reaction conditions. The reaction of benzyl phenyl and dibenzyl sulfide in aqueous acetic acid gave the corresponding sulf oxides with a small amount of cleavage products of the C-S bond. The reaction of benzyl phenyl sulfide in aqueous sodium hydroxide and dichloromethane gave the brominated sulfones.
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Content Type |
Departmental Bulletin Paper
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Text Version |
publisher
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Accession No. | KJ00005091754
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