ID | 1404 |
FullText File | |
Title Alternative | Oxidation of Benzyl Alcohols with Tetraalkylammonium Dichlorobromate(1-)
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Authors |
Negoro, Takeshi
Tanaka, Takanori
Taketomo, Hisae
Fujita, Yuki
Yano, Kozue
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Self DOI | |
Journal Title |
Bulletin of the Faculty of Education, Wakayama University. Natural science
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ISSN | 13424645
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NCID | AN00257977
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Volume | 53
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Start Page | 7
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End Page | 18
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Order | 04
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Published Date | 2003-02-27
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Language |
eng
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Abstract Alternative | The reaction of various substituted benzyl alcohols with an equimolar amount of tetraalkylammonium dichlorobromate(1-) (1) in water-hexane in the presence of sodium hydroxide gave the corresponding benzaldehydes and with 2 equiv. of 1 in water in the presence of sodium hydroxide (subsequent acid hydrolysis) gave the corresponding benzoic acids, respectively, in good yields. Meanwhile, the reaction of methoxy-substituted benzyl alcohols in the presence of disodium phosphate gave nuclear bromo-substituted benzyl alcohols.
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Content Type |
Departmental Bulletin Paper
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Text Version |
publisher
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Accession No. | KJ00000162679
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