DSC,X線,UV-Visスペクトル測定による臭素架橋一次元白金錯体の構造相転移とサーモクロミズム現象の研究

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ID 1443
FullText File
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Title Alternative
Phase Transition and Thermochromism in Bromo-Bridged 1-D Pt Complex Studied by DSC, X-ray and UV-Vis Spectrum Measurements
Authors
Nakamura, Akane
KIMURA, Noriyoshi Faculty of Education 和歌山大学研究者総覧 researchmap
Self DOI
10.19002/AN00257977.56.31
Journal Title
Bulletin of the Faculty of Education, Wakayama University. Natural science
ISSN
13424645
NCID
AN00257977
Volume
56
Start Page
31
End Page
33
Order
08
Published Date
2006-02-28
Language
jpn
Abstract Alternative
We performed the DSC, X-ray and UV-Vis spectrum measurements on [Pt (en)_2] [PtBr_2 (en)_2] (ClO_4)_4 in which a modification was reported by crystallizing from aqueous solution below room temperature. A metastable phase crystallizing below room temperature showed a different phase transition with thermochromism at ca. 380K to the stable form. The obtained X-ray powder patterns confirmed that the phase transition at 380K was transformation into the stable form.
Content Type
Departmental Bulletin Paper
Text Version
publisher
Accession No.
KJ00004438614